To prepare salsa, in a medium bowl combine pineapple, red pepper, onion, lime juice, 1 teaspoon chili powder, jalapeno pepper, 1/8 teaspoon cumin and cayenne. Season to taste with salt and pepper; set aside.
Blend seasoning with oil as needed to form a paste and rub over the chops. Heat a large heavy skillet over medium-high heat and mist or drizzle with oil. Sear chops quickly, cooking to 145-160 degrees internal (about 5-8 minutes), rest five minutes and serve with the salsa.
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